关键词: 树枝状大分子, 手性催化剂, 对映选择性, 不对称催化

Abstract: According to the different locations of chiral catalytically active species in Dendrimer，the progress of core or periphery functionalized chiral Dendrimer catalysts and polymer-supported chiral dendrimer catalysts synthesis and their application in asymmetric hydrogenation，asymmetric transfer hydrogenation，asymmetric Michael addition，asymmetric borane reduction of ketones，asymmetric aldol reaction，asymmetric diels-alder reaction is reviewed，which emphasizes the Dendritic structure and generation effects on the activity，enantioselectivity and recycling of chiral Dendrimer catalysts. And also prospects the future of recyclable chiral Dendrimer catalysts with high activity，stability and selectivity.

Key words: Dendrimer, chiral catalysts, enantioselectivity, asymmetric catalysis